Acá dejo un ejemplo de Libro de Guías, ya paso la certificación
<?xml version="1.0" encoding="ISO-8859-1"?>
<LibroGuia xmlns="http://www.sii.cl/SiiDte" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" version="1.0" xsi:schemaLocation="http://www.sii.cl/SiiDte LibroGuia_v10.xsd">
<EnvioLibro ID="IECV201312">
<Caratula>
<RutEmisorLibro>2-7</RutEmisorLibro>
<RutEnvia>8046219-0</RutEnvia>
<PeriodoTributario>2000-01</PeriodoTributario>
<FchResol>2013-12-09</FchResol>
<NroResol>0</NroResol>
<TipoLibro>ESPECIAL</TipoLibro>
<TipoEnvio>TOTAL</TipoEnvio>
<FolioNotificacion>1</FolioNotificacion>
</Caratula>
<ResumenPeriodo>
<TotFolAnulado>0</TotFolAnulado>
<TotGuiaAnulada>1</TotGuiaAnulada>
<TotGuiaVenta>1</TotGuiaVenta>
<TotMntGuiaVta>593742</TotMntGuiaVta>
<TotMntModificado>0</TotMntModificado>
<TotTraslado>
<TpoTraslado>5</TpoTraslado>
<CantGuia>1</CantGuia>
<MntGuia>0</MntGuia>
</TotTraslado>
</ResumenPeriodo>
<Detalle>
<Folio>4</Folio>
<Operacion>1</Operacion>
<TpoOper>5</TpoOper>
<FchDoc>2013-12-24</FchDoc>
<RUTDoc>2-7</RUTDoc>
<RznSoc>IMPORTADORA</RznSoc>
<MntNeto>0</MntNeto>
<TasaImp>0.00</TasaImp>
<IVA>0</IVA>
<MntTotal>0</MntTotal>
<MntModificado>0</MntModificado>
</Detalle>
<Detalle>
<Folio>5</Folio>
<Operacion>1</Operacion>
<TpoOper>1</TpoOper>
<FchDoc>2013-12-24</FchDoc>
<RUTDoc>7321267-7</RUTDoc>
<RznSoc>ALDO MOYANO ARANCIBIA</RznSoc>
<MntNeto>498943</MntNeto>
<TasaImp>19.00</TasaImp>
<IVA>94799</IVA>
<MntTotal>593742</MntTotal>
<MntModificado>0</MntModificado>
<TpoDocRef>33</TpoDocRef>
<FolioDocRef>17</FolioDocRef>
<FchDocRef>2013-12-24</FchDocRef>
</Detalle>
<Detalle>
<Folio>6</Folio>
<Anulado>2</Anulado>
<Operacion>1</Operacion>
<TpoOper>1</TpoOper>
<FchDoc>2013-12-24</FchDoc>
<RUTDoc>99225000-3</RUTDoc>
<RznSoc>ACE SEGUROS S.A.</RznSoc>
<MntNeto>0</MntNeto>
<TasaImp>19.00</TasaImp>
<IVA>0</IVA>
<MntTotal>0</MntTotal>
<MntModificado>0</MntModificado>
</Detalle>
<TmstFirma>2013-12-24T11:43:49</TmstFirma>
</EnvioLibro>
<Signature xmlns="http://www.w3.org/2000/09/xmldsig#">
<SignedInfo>
<CanonicalizationMethod Algorithm="http://www.w3.org/TR/2001/REC-xml-c14n-20010315"></CanonicalizationMethod>
<SignatureMethod Algorithm="http://www.w3.org/2000/09/xmldsig#rsa-sha1"></SignatureMethod>
<Reference URI="#IECV201312">
<Transforms>
<Transform Algorithm="http://www.w3.org/2000/09/xmldsig#enveloped-signature"></Transform>
</Transforms>
<DigestMethod Algorithm="http://www.w3.org/2000/09/xmldsig#sha1"></DigestMethod>
<DigestValue>68OzDQNtfXdHlTiDEpKNO1xwePk=</DigestValue>
</Reference>
</SignedInfo>
<SignatureValue>Kkl+25V5BNzZq9PlaU4/UMv+lg440sVObT4KK5cXtH+8oHTxGHIwcPyFPFBxBz8zhFzMzOUJ82pC
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Kpu9n92ZkoWvF+o8VAo=</SignatureValue>
<KeyInfo>
<KeyValue>
<RSAKeyValue>
<Modulus>xq8ZmBHRCVysfjZ+D3ImC/QUqmlpru0QxLKs+FPEKWKTHjMhV3GGExy8aNx7TBOyQsukY+4LNOgv
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37x7TN/Citw/2Ntj6Ps=</Modulus>
<Exponent>AQAB</Exponent>
</RSAKeyValue>
</KeyValue>
<X509Data>
<X509Certificate>MIIFyjCCBLKgAwIBAgIDAMF3MA0GCSqGSIb3DQEBBQUAMIGmMQswCQYDVQQGEwJDTDEYMBYGA1UE
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V3wBdQ==</X509Certificate>
</X509Data>
</KeyInfo>
</Signature>
</LibroGuia>
